Zero: The main protagonist of the series, Zero is traveling to the Alola region to gather information about his parents and to find his friend Dragonite.
Wartortle: His first Pokemon, he got him as an egg from Ryan. (He is basically the Pikachu for Zero)
Litten: Zero's Starter Pokemon from Alola.
Axew (Bal): A mysterious Axew Baby with a sun birthmark, found by Zero (as an Egg) this little Axew has a big secret.
The Main Female for the series she wants to be a Pokemon Fashion star.
Rowlet: Usagi's starter Pokemon.
Ralts (Luna): A Ralts with a Moon Birthmark and the Pokemon she had ever since she was a baby.
A rival to and traveling companion to Zero.
Popplio: Hau's Starter Pokemon.
The helper of The Professor of Alola and is holding a secret which could shake the Pokemon world to it's core.
Smergal: Her partner Pokemon
Pokemon Not owned by the group but Follow them
Rotom: A talking Rotom from the professor to help the heros with there Journey.
Magearna (Gear-Chan): A mysterious Pokemon found by the heros early on. This Pokemon holds information about the whereabouts of Zero's parents however it's memories are scattered throughout the region. It is currently an unofficial member of Zero's Team. It is also pursued by an evil organization.
Pokemon Sun and Moon Fan series Op: Burst! Pokemon! LET'S GO! (Pokeball spins in a void) Become the ultimate Trainer! (Zero grabs the Pokeball) Burst X4 POKEMON BURST! (Main characters run across a road into the sunrise) Burst X4 (Pokemon Sun Moon logo) Everyone's got it the desire to win and a battle style for them (The main characters make breakfast and train) Let's face it with each other now! You need the will to get stronger as hot as the SUN! BURST (Galdion sits on a cliff with his partner Pokemon) Dream! Tell your dreams to the MOON! BURST! (Zero thinks about his parents and see's them in the moonlight) Burn strong and burst past the limits you never kneeewwwwww! (Zero sends out Axew into battle who rapidly evolves into Haxerus) Zero: BURST EVOLUTION! When two people who've got the drive to win meet battle it out! (Zero faces off against blanked out trial captains) Or make bonds, a wonderful power is born! Burst X5 Usagi: BURST EVOLUTION! (Ralts evolves into Gardivoir) When it's time for the climax face it together! (The main characters battle Team Skull) Don't stop and finish it with your best! BURST! Everyone: BURST EVOLUTION! POKEMON! (End)